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Although the sodium cobaltinitrite is soluble in water, it forms the basis of a quantitative determination of potassium, thallium, and ammonium ions. Under the recommended reaction conditions the insoluble double salt, K2Na[Co(NO2)6]·H2O is precipitated and weighed.
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Related Information::
1.583 g of potassium chloride in water, and dilute with water to 500 mL. To 10.0 mL of this solution (20 mg of K2O) in a 50 mL beaker, add 2 mL of 1 N nitric acid and 8 mL of water. Dissolve 5 g of the sodium cobaltinitrite in water, dilute with water to 25 mL, and filter.