ACETONITRILE LR MSDS
| Product Name | RXSOL-60-6508-001 |
| Product Type | ACETONITRILE LR |
| Revised date | 27-04-2019 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| mail@rxmarine.com |
Substance / Preparation : Preparation.
Substance name Contents CAS No
Acetonitrile : 99.9% 75-05-8
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4)
H332
Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312
Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319
Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302
Physical hazards : Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) H225
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : F : Highly flammable
Xn : Harmful
R Phrase(s) : R11 : Highly flammable.
R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed.
R36 : Irritating to eyes.
S Phrase(s) : S1/2 : Keep locked up and out of reach of children.
S16 : Keep away from sources of ignition - No smoking.
S36/37 : Wear suitable protective clothing and gloves.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H225 : Highly flammable liquid and vapour.
H302 : Harmful if swallowed.
H312 : Harmful in contact with skin.
H319 : Causes serious eye irritation.
H332 : Harmful if inhaled.
Precautionary statements
• General : P102: Keep out of reach of children.
P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P233: Keep container tightly closed.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
• Response : P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you feel unwell.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated
clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P337+P313: If eye irritation persists: Get medical advice/attention.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P235: Store in well-ventilated place. Keep cool.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor if
you feel unwell.
Skin contact : Wash with plenty of soap and water. Wash contaminated clothing before
reuse. Specific treatment (see on this label). Remove/Take off immediately all
contaminated clothing. Immediately call a POISON CENTER or doctor.
Eye contact : Get medical advice. If eye irritation persists : Remove contact lenses, if
present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes.
Ingestion : Obtain emergency medical attention. Call a POISON CENTER or doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Repeated exposure to this material can result in absorption
through skin causing significant health hazard. Causes serious eye irritation. Danger of
serious damage to health by prolonged exposure through inhalation.
Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
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5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Highly flammable liquid and vapour.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual vapours are flammable.
Use only outdoors or in a well-ventilated area. Avoid breathing dust, fume, gas, mist,
vapours, spray. Do not eat, drink or smoke when using this product. Wash thoroughly
after handling.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed. Use explosion-proof electrical, ventilating, lighting, …, equipment.
Special precautions : No naked lights. No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep in
fireproof place. Ground/bond container and receiving equipment. Keep container tightly
closed.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
• Hand protection : Wear protective gloves.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
Occupational Exposure Limits : Acetonitrile : ILV (EU) - 8 H - [mg/m³] : ( 70 Skin. )
Acetonitrile : ILV (EU) - 8 H - [ppm] : ( 40 Skin. )
Acetonitrile : VLA-ED [ppm] : 40
Acetonitrile : VLA-ED [mg/m³] : 68
Acetonitrile : VLA-EC [ppm] : 60
Acetonitrile : VLA-EC [mg/m³] : 102
VLA-ED [ppm] : 40
VLA-ED [mg/m³] : 68
VLA-EC [ppm] : 60
VLA-EC [mg/m³] : 102
ILV (EU) - 8 H - [ppm] : ( 40 Skin. )
ILV (EU) - 8 H - [mg/m³] : ( 70 Skin. )
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -480C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 525
Flammability (solid, gas) : Flammable.
Highly flammable liquid and vapour.
Flash point [°C] : 20C
Boiling point [°C] : 81
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : 5.8
Vapour pressure [20°C] : 9.7kPa
Vapour pressure mm/Hg : 73
Vapour density : 1,4
Density [g/cm3] : 0,79
Relative density, gas (air=1) : 1,4
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Complete.
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 7
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
May release flammable gases.
11.1. Information on toxicological effects
Toxicity information : The product has been not fully tested. The calculated risk has
been done under the requirements of the EU regulations.
Acute toxicity.
• Inhalation : Harmful if inhaled.
• Dermal : Harmful in contact with skin.
- LD50 Rabbit dermal [mg/kg] : 50
• Ingestion : Harmful if swallowed.
- Rat oral LD50 [mg/kg] : 100
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes serious eye irritation.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not
met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : The product has been not fully tested. The calculated risk has
been done under the requirements of the EU regulations.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations.
Dispose of this material and its container to hazardous or special waste collection
point, in accordance with local, regional, national and/or international regulation.
Special precautions : Handle empty containers with care because residual vapours are
flammable.
14.1. Land transport (ADR-RID)
Proper shipping name : ACETONITRILE
UN N° : 1648
H.I. nr : 33
ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid.
ADR - Classification code : F1
ADR - Group : II
ADR - Packing instructions : P001 R001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of
category D and
E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ACETONITRILE
UN N° : 1648
IMO-IMDG - Class or division : 3 : Flammable liquid.
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-D
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ACETONITRILE
UN N° : 1648
IATA - Class or division : 3 : Flammable liquid.
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 353
instruction
- Passenger and Cargo - Maximum : 5 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 364
- Cargo only - Maximum Quantity/ : 60 L
Packing
IATA - Limited Quantites : 1 L
ERG-Nr : 3L
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
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