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Per acetic acid or PAA HEALTH HAZARD INFORMATION

HEALTH HAZARD INFORMATION SHEET Peroxyacetic Acid (PAA)

Peroxyacetic acid (also known as peracetic acid or PAA) is an organic peroxide based, colorless liquid with a low pH and a strong, pungent, vinegar-like odor. In the concentrated form it is highly corrosive and unstable. PAA is formed from the reaction of acetic acid and hydrogen peroxide. Commercial PAA products contain all three chemicals in an aqueous solution often with stabilizers added. The concentration of PAA as the active ingredient, as well as the mixture of the other ingredients, can vary widely.

PAA is used in food and beverage industries as well as hospitals, health care and pharmaceutical facilities as an antimicrobial agent, surface cleaner and sanitizer. In many meat and poultry establishments it is used on carcasses, parts, trim and organs to reduce bacterial contamination and foot spoilage. It can be applied by a variety of methods including spray cabinet, dip tank, hand spray pump and chiller.

How are FSIS employees potentially exposed to PAA in their workplaces?

FSIS employees can potentially be exposed to PAA when it is used as an antimicrobial or acidifier in ways that fail to properly contain or ventilate the product. The following are some examples of how IPP could potentially be exposed if controls are not properly in place:

  • Off-gassing from chillers;

  • Over spray from spray cabinet openings and high nozzle pressure;

  • Lack of local exhaust ventilation on spray cabinets;

  • Inadequate ventilation in kill floor area;

  • Direct discharge of waste solution from cabinets and tanks directly onto the floor;

  • Failure to properly control solution pH;

  • Chemical mixing in floor drains; and

  • Hand application with spray tanks.

The latest version of FSIS Directive 7120.1, “Safe and Suitable Ingredients Used in the Production of Meat, Poultry, and Egg Products”, contains a list of PAA containing substances and the concentrations that may be used for specific purposes in meat, poultry and egg product establishments. PAA solutions are currently approved for use in PAA concentrations ranging from 50 to 2,000 parts per million (ppm).

ESHG-Health-03.00 FSIS Environmental, Safety and Health Group (ESHG) 1

What are the potential health effects of exposure to PAA?

Concentrated forms of PAA solution are corrosive and exposure can cause irreversible damage to skin and eyes. When PAA is used in establishments for antimicrobial applications, it is used in diluted concentrations (ranging from 50 to 2,000 ppm in solution). Exposure to PAA in the dilute form as a vapor or mist may sometimes cause eye, nose, throat and respiratory irritation that usually subsides when exposure ceases. Currently, there is no correlation between a specific concentration in solution and the resulting concentration in air or the level of irritation expected. IPP should be aware that, in general, pre-existing respiratory conditions may be aggravated by exposure to airborne irritants.

What OSHA Standards and exposure guidelines apply to PAA?

There are no specific OSHA standards for PAA. The American Conference of Governmental Hygienists (ACGIH) recommends a Threshold Limit Value (TLV) of 0.4 ppm, as a 15-minute Short Term Exposure Limit (STEL). ACGIH also does not consider PAA to be classifiable as a human carcinogen.

The ACGIH TLV is currently used in the meat and poultry industry as a general guideline for determining PAA health exposures. Therefore, when airborne concentrations of PAA exceed this value, action should be taken to limit exposure by leaving the work area until the reason for the elevated concentration can be identified and resolved.

The National Institute for Occupational Safety and Health (NIOSH) is in the process of determining the concentration of PAA that should be considered Immediately Dangerous to Life and Health (IDLH). This document will be updated with that value when it is published.

How are occupational exposures to PAA monitored or measured?

There are no validated OSHA or NIOSH air sampling methods for PAA. Both agencies are investigating and developing a reliable method. This document will be updated when more information if available.

ESHG-Health-03.00 FSIS Environmental, Safety and Health Group (ESHG) 2

There are also several portable, direct reading monitors which are commercially available for sampling PAA. However, these monitors are not specific for PAA but can react to many types of oxidizing chemicals (such as chlorine, ozone and hydrogen peroxide). The monitor sensors are also sensitive to water, humidity and temperature making them difficult to use reliably in many establishments where PAA is used. The FSIS Environmental, Safety and Health Group (ESHG) is currently evaluating these monitors for use in the field.

What safety precautions can be followed to protect FSIS employees against exposure to PAA?

The most effective ways to prevent over-exposure to PAA is to minimize the amount of vapor, mist or droplets that come into direct contact with employees by providing adequate containment, ventilation, and process controls.

Some potential controls that establishments can put in place to minimize exposure are :

• Spray cabinets can be enclosed enough so that significant amounts of mists or droplets are not released through the entrance or exit to the cabinet.
• Local exhaust ventilation can be used to remove mists directly from the

cabinets.
• Clear plastic or stainless steel shields can be used to deflect spray from

contacting inspectors.
• Spray cabinets can be installed as far as practical from inspection stations. • Closed drain lines can be used for wastewater discharges from the cabinets

to the floor drains.
• If there is an issue with chemical mixing in floor drains, a dedicated drain line in the floor troughs can be used to carry the wastewater to an area where discharge will not cause safety issues.

• Adequate general ventilation can be provided using properly designed exhaust fans and fresh air supply units.

• PAA solutions can be monitored and controlled for concentration, pH, and temperature to reduce off-gassing, as specified by the system supplier.

How can an IIC ensure compliance with the OSHA Hazard Communication Standard for this Chemical?

1. The IIC is responsible for ensuring that the requirements of FSIS Directive 4791.5, “Hazard Communication Program” are met.

This includes:

ESHG-Health-03.00 FSIS Environmental, Safety and Health Group (ESHG) 3

• Ensuring the List of Hazardous Chemicals used or stored on site is available in the USDA office as required by Directive 4791.5 Attachment 1 Section II. This list is usually limited to antimicrobials, sanitizers, and refrigerants.

• The Safety Data Sheet (SDS) library location is noted on the signature page of Directive 4791.5 Attachment 1.

• Ensuring hazardous chemical containers are appropriately labeled.

2. The IIC is to provide training to all FSIS employees (including relief inspectors) for all chemical hazards in the workplace. Training includes:

  • Allowing IPP access to and time to read the SDS.

  • The location of hazardous chemicals that IPP may be exposed under routine and emergency conditions.

• Monitoring systems (if any) used to detect the presence or release of a hazardous chemical in the work area.

• How IPP can identify the presence or release of a hazardous chemical (e.g. visual appearance or odor of chemicals).

  • The location of the required list of chemicals.

  • The location of the SDS library.

  • Steps IPP can take to protect themselves from hazardous exposure.

  • Emergency procedures found on FSIS form 4791-21.

4. The IIC can use information from the SDS and the chemical label for training material and any additional information provided by the chemical supplier and/or establishment regarding the working solutions and use concentrations to which IPP may be exposed in their work areas.

All occupational health and safety training is to be recorded using either AgLearn or FSIS form 3530-12. Training records are to include the topics covered, date, and employee name. The Agency is to retain all training records for a minimum of five years.

 

Why Ferroxyl Test Kit?

Free iron cannot be seen on the surfaces of contaminated parts. Therefore, it must be converted into a visible form.   
Ferroxyl Test Kit helps to Identify transition Iron metal ions to blue colour spot. 

The transition of Iron metals to form blue coloured compounds with TK F1 and TK F2. 

colourless solution → blue precipitate  ( Detail of Ferroxyl test kit procedure and specification are available on this link http://rxmarine.com/Ferroxyl-Test-Kit-for-free-IRON

We are one of popular Ferroxyl Test Kit seller and supplier in Mumbai, Visakhapatnam, Chennai, Kolkata, Gandhidham, Fujairah, Dubai, Sharjah, Abu Dhabi. Ferroxyl test kit are available on discounted price to our regular customer. Please share your requirement through this email id mail@rxmarine.com for India supply while you can use this email id mail@dubichem.com if your location is middle east.

When Phosphoric Acid can be used as Fertilizer?

When PHOSPHORIC ACID can be used :

Phosphoric Acid is used as fertilizer ::: It is important, what the soil in your yard (field). If the pH is 6,5 -7, then everything is fine. But for acidic soil if pH < 6, avoid uses of phosphoric acid will increase the acidication of soil, which can damage most crops. In this case it is possible to add sodium carbonate or potassium carbonate.

DOSE of Phosphoric Acid : 
Apply the H3PO4 can be a fertilizer of different cultures. If the acid is concentrated, the dosage should be no more than 18 g per 10 liters of water.

Email ::: mail@rxmarine.com

Phosphoric Acid Supplier in Nairobi Kenya Africa, Fujairah Dubai UAE, Muscat Barka Oman

How To Prevent Silver And Jewelry From Tarnishing Using Silica Gel?

If you inherited beautiful antique silverware, you probably hate polishing the forks, spoons, and knives before every use. Cut down on tarnish by storing your silver with a silica gel packet or two. The desiccants help prevent corrosion by absorbing moisture, which reacts with sulfur in the atmosphere to create tarnish. This trick also works with jewelry, so add a gel packet to your jewelry box to keep your bling looking its best

BUY SILICA GEL NOW FROM RX MARINE INTERNATIONAL.

MAIL US AT: mail@rxmarine.com

What are the advantages of using Orange Silica Gel?

THE ADVANTAGES ARE AS FOLLOWS:

1Indicating status of silica gel without cobalt chloride.

2Non - toxic and non flammable silica gel

3Environmental friendly type

4Acceptable worldwide especially in European countries.

5Higher absorption Capacity at low RH

Contact us for any queries:

Mail us at: mail@rxmarine.com

 

What is the difference between blue silica gel and orange silica gel?

1.Blue indicating silica gel contains cobalt chloride and is therefore extremely toxic for human use. Whereas, orange indicating silica gel does not contain cobalt chloride but contains methyl violet.

2.The cobalt chloride in blue silica gel allows it to change color from blue (when dry) to pink (when wet). Whereas, orange indicating silica gel changes from orange (when dry) to green (when wet).

RX MARINE INTERNATIONAL has ready stock of all three different color indicating silica gels in Mumbai, Gandhidham, Chennai, Vishakhapatnam, Kolkata, Fujairah and Oman.

Contact us for any queries:

Mail us at: mail@rxmarine.com

What is the Dosing ration of Cool Treat and Biocide in Cooling water System?

1.Nitrite Based COOL TREAT is to be added at a rate of 5 liters per 1,000 liters of the CW system capacity 

2.MICROTREAT Micro biocide is to be added immediately after dosing with COOL TREAT at 2.5 liters per 1,000 liters of system of system capacity

#CoolingWaterTreatmentChemicals
#CoolWaterTreatment

 

Whats the benefit of Antiscalant Corrosion Inhibitor for Engine?

RXSOL 2000 Antiscalant Corrosion Inhibitor Application: All types of Engine Jackets, Radiator and Engine coolant.

The stable oxide film that is formed by RXSOL 2000 prevents corrosion caused by electrolytic action between dissimilar metals used in the system . RXSOL 2000  has been field tested and found to have no detrimental effects on non metallic substances such as seals, glands, packing, hoses, gaskets etc., normally used in these’ systems.

Application-Dg*

Sets Internal combustion engines closed circuit cooling system compressor cooling system. Rxsol 2000-II  incorporates superior corrosion inhibitors to prevent corrosion works by free of scale deposits.

Advatages benefit of Antiscalant Corrosion Inhibitor RXSOL 2000 for Engine : -

1. Prolong the life of equipment by keeping scale and corrosion free. Since RXSOL 2000 Ltr is alkaline and so will suppress acid corrosion, which would otherwise result in corrosion damage such as pitting. However, the alkalinity control is such that even if the product is accidentally overdosed, the pH of the water will remain within limits. The metals which would be affected by extremes of alkalinity or acidity are protected. protect cast iron diesel engine cooling systems.

2. Improves generating cooling efficiency by maintaining a clean heat transfer by protect against sludge and mineral scale formation.

3. Corrosion protection by using superior corrosion inhibitor.

4. Reduced maintenance and down time

5. Compatible with Coolants / Antifreeze solution / Glycol .

6. Friendly with Metals (Like steel, Copper, Aluminum, all alloys) & Non-metal (Rubber, Hoses, Gasket , and ‘O’rings.etc.)

7. Prevents over heating Effective against liner pitting and cavitation erosion.

NOTE :::
•Protects both ferrous and non-ferrous metals from oxygen & corrosion.
•Compatible with most coolants and anti frizzles.
•Non staining.

Antiscalant Corrosion Inhibitor RXSOL 2000 manufacturer and supplier in India, Oman, UAE, Sudan, Yemen, Kenya Nairobi

How to suppress Acid corrosion from Heat Transfer system like Radiator, DG Sets, Chiller Cooling water system, Closed cooling Water Circuit of diesel / petrol engine, Ice Water system etc.

How to suppress Acid corrosion from Heat Transfer system like Radiator, DG Sets, Chiller Cooling water system, Closed cooling Water Circuit of diesel / petrol engine, Ice Water system etc.

 

RXSOL Roccor Nitrite Borax based Corrosion inhibitor Prolongs the life of equipment by keeping it scale and corrosion free. Since ROCCOR NB RXSOL-40-4001-025 is alkaline which effectively neutralize the ACIDIC corrosion affect.

 

The initial dosage  of ROCCOR Nitrite Borax based corrosion inhibitor for an untreated system is 8 liters of product per 1000 liters of water. Such a dose will bring nitrite levels over 1200 ppm. Maximum nitrite level is considered to be 2400 ppm. Frequent tests should be carried out in order to maintain pH values within the limit (8.3-10.0), while levels of chloride should be maximum 50 ppm.

Corrosion Inhibitor for Cooling water System supplier in Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Haldia, Paradip, Fujairah, Dubai, Ajman, Sharjah.

Mail us to get discounted price of Corrosion Inhibitor Roccor NB cooling water treatment chemicals. ::: mail@rxmarine.com

DOSES and Using procedure of Nitrite Borax Corrosion Inhibitor?

DOSES and Using procedure of Nitrite Borax Corrosion Inhibitor?

 

GENERAL RECOMMENDATION : ( The dosage chart may be used as a guide to adjust treatment to obtain the optimum level.)

 

Nitrite (as PPM NO2) 0 100-200 300-600 700-900 1100-1300   

RXSOL-40-4001-025 / 1000L 8.0 7.3 7-8 5-7  1.5-3.5

NOTE ::: --   If nitrite level becomes 1440-2400 then doses should be ZERO.

 

 

The initial dosage for an untreated system is 8 liters of product per 1000 liters of water. Such a dose will bring nitrite levels over 1200 ppm. Maximum nitrite level is considered to be 2400 ppm. Frequent tests should be carried out in order to maintain pH values within the limit (8.3-10.0), while levels of chloride should be maximum 50 ppm.

 

Initial dosage for an untreated system is 9 litres of RXSOL-40-4001-025 / 1000 litres of untreated distilled water. This will bring the treatment up to the minimum level of 1000 ppm nitrite. For best result and prolonged engine life add RXSOL-40-4001-025 every 500 -6500 km. or 250 to 300 hours of running time or every 2 month interval. Specially designed for use in  water systems of internal combustion equipment. pH should be maintained between 8.3 and 10 by the treatment.

 

RXSOL-40-4001-025 will react with sludge and in most cases, facilitate sludge gradual removal. On badly fouled systems with oil or scale, a prior degreasing by using DEGREASER HEAVY DUTY or descaling by using DEGREASER HEAVY DUTY, SCALE REMOVER LIQUID or SCALE REMOVER POWDER is highly recommended.

 

 

• Excellent corrosion inhibitor for cooling water

 

• Minimises metal oxide deposits

 

• Protects ferrous and non-ferrous metals

 

• Compatible with glycol-based antifreeze

 

• Reduces cleaning & maintenance costs

 

• Cost effective, easy to apply and use

 

How to Protect internal combustion engines, compressors, chiller system and DG sets from Corrosion from Nitrite Borax Corrosion Inhibitor Liquid?

 

Nitrite Borax Corrosion Inhibitor is a  unique formulation with highly concentrated liquid cooling treatment compound, ferrous & Non ferrous corrosion inhibitors, antiscalants, dispersant and buffer solution of non carbonate.

 

Nitrite Borax Corrosion Inhibitor is specialized such a way which can be use in high or low temperature closed cooling water systems for the prevention of corrosion and scale formation in internal combustion engines, compressors, chiller system and DG sets. Also Usefull to Protects all metals including cast iron, mild steels and copper. Recommended ppm levels are easily controlled by standered RXSOL test kit Nitrite / Chloride.

 

 

The stable protective microfilm prevents corrosion caused by electrolytic action and the alkaline nature of this product prevents acid attack.

 

The stability of the added polymers are very useful for water treatment processes. Such polymers with low molecular weights cannot only inhibit calcium, magnesium, and silica scale in cooling towers and boilers, but also help corrosion control by dispersing iron oxide. 

 

FIELDS ::: --- Suitable for use in closed water cooling systems, ice melting systems and transformer cooling systems. The product may be used in all kinds of diesel & petrol engines, compressor or heating cooling water circuits.

 

Where Nitrie Borax Corrosion Inhibitor can be used?

 

Prolongs the life of equipment by keeping it scale and corrosion free. Since RXSOL-40-4001-025 is alkaline, it will suppress acid corrosion, which would otherwise result in sever pittings. It improves cooling efficiency by maintaining clean heat transfer surfaces , from Radiators, DG - sets, Closed Cooling and chiller System.

 

FIELDS ::: --- Suitable for use in closed water cooling systems, ice melting systems and transformer cooling systems. The product may be used in all kinds of diesel & petrol engines, compressor or heating cooling water circuits.

 

 

( Used as a corrosion inhibitor for all ferrous and non-ferrous metals found in water systems )

 

 

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